I've just been looking at your colours, I think the Dulux Dieskau would work the best with the other colours you have to work with, choosing colours is such a personal thing and I know it can be really hard to choose and hope you make the correct choice. Oskuee is right, a paint job can look terrible half way through so you need to make sure you finish to get the proper look of colour. But the biggest thing to remember is it's only paint and it's the cheapest thing to change so if your not happy with the colour you choose you can always try something else. Happy redecorating :)

I agree but my comment means that my opinion is that colour and the way to find out would be as you say in person at a paint store but I reiterate that I have a very trained eye for colour and can only go by the sample above the rest is up to the home owner.

some photos would explain the dilemma

As said by big reader...leave white or paint the same colour, without the brushed finish, on the other walls. You can not bring another colour in. There is enough colour already with the orange wood and the bed cover. Also, the curtains look too small to pull right across your window correctly. They should be waved not flat when closed.