Many years ago, we had a friend that wanted to make his whole house out of exposed concrete with curving walls................. wonder what ever happened to him?? As for me, ah, no!

Thanks for that! Why not submit it for a Houzz article?

In my last house, after adding a living room (the area you see this side of the arch) and also updating bathroom etc I couldn't afford to reline the ancient walls in my little lounge (when I removed the purple wallpaper I found a mixmax of boards, gib, pinex, plywood and holes!) so I plastered walls all over with layers and layers of newspaper and wallpaper paste (papier mache), then after applying primer/undercoat I painted with 2 similar colours (rich reds in this case), and stippled the surface with a plastic bag. This made it look just very slightly textured like leather and successfully disguised the uneven surfaces. Gallons of gap filler filled the gaps between the old T&G ceiling boards and evened out the mismatched skirting and scotia. Again white paint on all the trims. Amazing what can be done when you have to make do! This was a great cosy little room! (Before photo is the 3rd one)

From what you have said, I think smaller separate pieces such as couch and chair(s) rather than a large sectional is likely to work better in the space and still allow for traffic flow. However, if you still have lots to do then don't rush to make large purchases. In the meantime, if your current sectional looks better pulled away from the wall a bit, then perhaps you could rotate the side table so that the long side runs parallel with the sofa arm instead of the wall. Would that help to stop it blocking the doorway and resolve the 'not quite right' placement?